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a 2 KClO3(s) 2 KCl(s) + 3 O2(g) You get 1 point if you have the above equation b (2/3 mole KClO3) (3 moles O2/2 moles KClO3) = 1 mole O2 You get 1 point for the correct answer and 1 point for the work You can get these points if you correctly use information from an incorrect equation in part a c At STP the volume of 1 mole of O2 should be 224 liters The volume is greater because oxygen was not the only gas in the sample Water vapor was present The presence of the additional gas leads to a larger volume You get 1 point for discussing STP and 224 liters, and 1 point for discussing the presence of water vapor d There are two acceptable equations; either will get you 1 point You do not need both equations

(1456)

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Equations (1455) and (1456) together constitute a thermodynamically sound mixing rule for q Application of Eq (1455) requires prior evaluation of Z and Zi from the equation of state These quantities are also required for evaluation of 1 and Ii by Eq (662b) However, the equation of state contains q, evaluated from the qi values through Eq (1456) Equations (1455) and (1456), together with Eq (1438) or Eq (1439) and the necessary auxiliary equations, must therefore be solved simultaneously for {Zi), Z, {Ii), I , {qi), and q, either by iteration or by the equation-solving feature of a software package The results make possible the calculation of $i values by Eq (1450) A choice must be made of an equation of state Only the Soave/Redlich/Kwong and PengJRobinson equations are treated here, and they usually give comparable results A choice must also be made of a correlating equation for the liquid-phase composition dependence of In yi The Wilson, NRTL, and UNIQUAC equations (Sec 122) are of general applicability; for binary systems the Margules and van Laar equations may also be used The equation selected depends on evidence of its suitability to the particular system treated The required input information includes not only the known values of T and {xi}, but also estimates of P and {yi},the quantities to be evaluated These require some preliminary calculations:

1 For the chosen equation of state (with appropriate values of a, r , and a),for each species Q, find values of bi and preliminary values of qi from Eqs (1434) and (1435) 2 If the vapor pressure PiSat for species i at temperature T is known, determine a new value for qi by iterative solution of Eq (1437) at P = Pisat with pi from Eq (1432), Zi and Ii for both liquid and vapor phases from Eqs (1431), (1433), and (662b) 3 A reasonable estimate of P is given by the sum of known or estimated PiSat values, each weighted by its known liquid-phase mole fraction 4 For each species i at the given T and estimated P , find liquid-phase values for Zi and Ii from Eqs (1433) and (662b) 5 For each species i at the given T and estimated P , find vapor-phase values for Zi and Ii from Eqs (1431) and (662b) 6 For each pure species i evaluate $ and $, by Eq (1136) : 7 An initial estimate of the vapor-phase composition is based on the assumption that both the liquid and vapor phases are ideal solutions Each fugacity coefficient is then given by $i = $i, and Eq (1453) can be written (Ki yi/xi):

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Since these values are not constrained to sum to unity, they should be normalized to yield the initial estimate of vapor-phase composition The essential step in the iterative process of Fig 148 is evaluation of {$f} and

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